Secret Messages with Elmer's Glue Sticks - An Acid-Base Indicator Activity

Elmer’s Disappearing Purple Glue is a standard school supply in most K-12 classrooms. Many students are familiar with its bright purple color that disappears as it dries on their school projects. 

How does it work?

The purple color comes from a dye called o-Cresolphthalein (Figure 1), an acid-base indicator closely related to the familiar phenolphthalein. o-Cresolphthalein is colorless below pH 8.2 and purple at a pH higher than 9.8. The indicator is purple in the glue stick due to the liquid water used in the glue formulation. When the water evaporates, the o-Cresolphathalein turns colorless (see Video 1 below).1

 

How Does Elmer's Disappearing Purple Glue Work? 🤔 #shorts #chemistry #science #experiment

Video 1: How Does Elmer's Disappearing Glue Work? The Science Classroom YouTube Channel, August 23, 2022.

 

 

Figure 1: o-Cresolphthalein

 

The activity described provides an interactive introduction to acid-base indicators. Students use paint brushes dipped in vinegar to write a secret message on a notecard, then messages are decoded by applying Elmer’s Disappearing Purple Glue. Since vinegar has a pH of around 2-3, the o-Cresolphthalein will appear colorless only where the vinegar is spread while remaining purple on the rest of the paper surface see Video 2 below.

 

Writing Secret Messages with Elmer's Glue 😃🧪 #shorts #chemistry #science #experiment #youtubeshorts

Video 2: Writing Secret Messages with Elmer's Glue, The Science Classroom, August 30, 2022.

 

References:

  1. Joginder KukrejaVan R. FosterDana L. Conover. (2012) High-Strength Gluestick Formulation with Color Indicator (U.S. Patent No. 13/587,264). U.S. Patent and Trademark Office.
Concepts: 
acid/base
indicators
Procedure time: 
15 minutes
Prep time: 
10 minutes
Time required: 

This activity can be completed in about 15 minutes.

Materials: 

Elmer’s Disappearing Glue Stick

Small amount of vinegar poured into a 100-mL beaker

Small paintbrush

Notecard

Blow dryer (optional)

Procedure: 
  1. Dip the paintbrush in the vinegar and then write a message on the notecard.
  2. Allow the vinegar to dry by waving the note card or blowing on it. (A blow dryer gives the best result because the words appear a lot sharper when completely dried).
  3. Apply glue to cover the notecard with an Elmer’s Disappearing Glue Stick and reveal the secret message.
Preparation: 

Gather materials and pour a small amount of vinegar in a 100-mL beaker.

Attribution: 

N/A

Collection: 

Safety

General Safety

For Laboratory Work: Please refer to the ACS Guidelines for Chemical Laboratory Safety in Secondary Schools (2016).  

For Demonstrations: Please refer to the ACS Division of Chemical Education Safety Guidelines for Chemical Demonstrations.

Other Safety resources

RAMP: Recognize hazards; Assess the risks of hazards; Minimize the risks of hazards; Prepare for emergencies