first-year undergraduate

Does ATP Provide Energy?

When using standard thermodynamic values, the chemical reaction whereby ATP is converted to ADP is found to have a positive value for ΔG. This would imply the reaction REQUIRES energy. However, analyzing the process under physiological conditions shows that ΔG is in fact negative, as expected.

Ramping Up the Disappearing Rainbow with the Assassin’s Water Bottle

What happens when chemistry and illusion collide? In The Disappearing Rainbow, a simple acid–base demonstration transforms into a spellbinding performance. With a single pour, colorless liquids bloom into a vibrant rainbow—then vanish in an instant. Now, with the arrival of the “Assassin’s water bottle,” this classic demo gets a modern twist that makes the magic easier (and cleaner) than ever.

Magnesium Citrate: Synthesis of a Pharmaceutical Compound at Time of Use

This post offers a case study of magnesium citrate used as a pharmaceutical. How does adding a dry white powder to water form aqueous magnesium citrate? To understand what occurs requires students to name chemical compounds, balance chemical equations, calculate theoretical yields, limiting and excess reagents, and use elemental percentage composition. A student question set is available as a resource.

Three Turmeric Treats

Curcumin, found in the spice turmeric, varies from yellow in acidic conditions to orange-red in basic conditions. This enables curcumin to be used in many acid-base demonstrations and incorporate ideas such as hidden messages and mechanochemistry.

The Value of Microtitrations

Microtitrations can be used as a stand-alone lesson or as an introduction to more complex titrations. Done without expensive glassware and materials, this alternative to buret titrations is easy to implement in most classroom situations.

Not so Green Up Close: a Peek at a dyed Chicago River Sample

Light absorbance and fluorescence were studied for a sample of the Chicago River that had been dyed green for St. Patrick’s Day. The sample had weak green fluorescence, showing that the intense green appearance of the river was in part due to the long path length of light through the water. The ability of the green color to partition into 1-octanol was also explored.