A General Method to Prepare Halogen-Free Oxalate Diesters for Peroxyoxalate Chemiluminescence Demonstrations
Chemiluminescence demonstrations that use peroxyoxalate “glowstick” systems are very popular in a variety of lecture demonstrations and classroom activities. These reactions are very eye catching and easy to do; however, until recently, the range of oxalate diesters available has been limited. In this article we present a modification of the published procedures for the preparation of multigram quantities of oxalate diesters derived from vanillin and methyl salicylate. The modified protocol allows a common procedure to be followed to access both compounds efficiently.