An Exact Value for Avogadro's Number

The currently accepted formal definition of a mole is the number of carbon-12 atoms in exactly 12 grams of the pure substace. This is not a good operational definition, however, because it takes too long to find, purify, and count all those atoms. The best experimental value is based on x-ray diffraction experiments on silicon crystals and puts the number within 0.0000010 of 6.0221415 x 10^23. However, that number is not satisfactory to the perceptive (read "smart aleck") student of chemistry who challenges his teacher with the fact that the definition requires that Avogadro's number be an integer. Because the definition of a (kilo)gram, represented by a platinum- iridium cylinder stored in Severes, France, changes slightly with calibration experiments and cleaning, the size of the mole theoretically changes proportionally. Fox and Hill, two noun-named professors at Georgia Tech, propose to define the kilogram in terms of a fixed value of Avogadro's number. Perhaps you and your students can determine why they chose the value they propose (602,214,141,070,409,084,099,072). Once you have defined NA, then the kilogram is determined and you can tell the keepers of the kilogram cylinder that their work is done.

Publication information
Pick Attribution: 

Ronald M. Fox and Theodore P. Hill

Publication Date: 
Friday, April 13, 2012