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Amines and Aniline

pH of aqueous ammonia, cyclohexylamine, and aniline, iodination of aniline, oxidation of aniline with benzoyl peroxide, the nitrous acid test, diazo coupling, reaction of luminol and light sticks are demonstrated.

pH of Aqueous Ammonia, Cyclohexylamine, and Aniline


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An electrode measures the pH of 0.1M aqueous solutions of ammonia, cyclohexylamine and aniline.

Iodination of Aniline


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Iodination of aniline is demonstrated.

Oxidation of Aniline with Benzoyl Peroxide


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Oxidation of aniline with benzoyl peroxide produces a puff of smoke.

Diazotization of Aniline Derivatives: Nitrous Acid Test


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The nitrous acid test is used to classify amines as primary, secondary, or tertiary.

Diazotization of Aniline Derivatives: Diazo Coupling


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Solutions of 4-nitroaniline and anthranilic acid in aqueous HCl are treated with sodium nitrite solution to form the corresponding diazonium salts.

Luminol


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Luminol is Demonstrated

Light Sticks


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Light sticks are demonstrated.