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Diazotization of Aniline Derivatives: Diazo Coupling

Solutions of 4-nitroaniline and anthranilic acid in aqueous HCl are treated with sodium nitrite solution to form the corresponding diazonium salts.

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5 MB, 78 seconds

File: MOVIES/TRAM14/0485410.MOV

Voiceover
Diazonium salts are useful for preparing dyes by coupling with nucleophilic reagents. Solutions of 4-nitroaniline and anthranilic acid in aqueous hydrochloric acid are treated with sodium nitrite solution to form the corresponding diazonium salts. These salts are treated with an aqueous solution of 2-naphthol. Red precipitates of diazo dyes form.

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Design, Text and Demonstrator:  
  Gary Trammell University of Illinois at Springfield, Springfield, IL 62794
Videographer/Editor:  
  Steve Dykema University of Illinois at Springfield, Springfield, IL 62794
Voice:  
  Margaret Biddle University of Wisconsin - Madison, Madison, WI 53706
Audio Production:  
  Greg Minix University of Wisconsin - Madison, College of Engineering, Madison, WI 53706
  Jerrold J. Jacobsen University of Wisconsin - Madison, Madison, WI 53706