Electrochemical Cells

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Description
Preparing the Meter
Preparing a Half-Cell
Preparing a Salt Bridge
Assembling the Cell and Measuring the Potential Difference
Additional Topics
Conventions in Electrochemistry
Zeroing the Meter
Self Check Exercises 1
Self Check Exercises 2
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Self Check Exercises 1

 

check Where does reduction occur in an electrochemical cell? Answer

Reduction occurs at the cathode, and oxidation occurs at the anode. (Note: Reduction and cathode both start with a consonant; and oxidation and anode both start with a vowel).

check If a cell is constructed from a tin half-cell and a silver half cell, which statement is true? (The half-cell potential for the silver half-cell is 0.80V, and the half-cell potential for the tin half-cell is -0.14V.)

  1. Ag(s) will be oxidized to Ag+(aq) and Sn(s) will be reduced to Sn2+(aq)
  2. Ag(s) will be oxidized to Ag+(aq) and Sn2+(aq) will be reduced to Sn(s)
  3. Ag+(aq) will be reduced to Ag(s) and Sn(s) will be oxidized to Sn2+(aq)
  4. Ag+(aq) will be reduced to Ag(s) and Sn(s) will be reduced to Sn2+(aq)

Since Ag+ has a more positive reduction potential, Ag+(aq) will be reduced to Ag(s). The tin reaction is reversed, and Sn(s) will be oxidized to Sn2+(aq).