JCE Software Chemistry Comes Alive!
Hydrolysis of tert-Butyl Chloride

This is a demonstration of the hydrolysis of tertiary butyl chloride.

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6.1 MB, 95 seconds

File: MOVIES/MISC/TBUTYL.MOV

Voiceover
0.1 molar hydrochloric acid is added to a solution of isopropyl alcohol, water and universal indicator. The solution is made basic with one molar sodium hydroxide. This is shown by the blue color of the indicator. Tertiary butyl chloride is added. As the slow hydrolysis of the chloride proceeds, the acidity of the solution increases, as eventually shown by the color of the indicator.

If more sodium hydroxide is added, the solution turns blue again.


Design, demonstration and text:  
  George Gilbert Denison University, Granville, OH 43023
Voice:  
  Kelly Houston Jetzer University of Wisconsin - Madison, Madison, WI 53706
Video:  
  Jerrold J. Jacobsen University of Wisconsin - Madison, Madison, WI 53706