JCE Software Chemistry Comes Alive!
Burning of Sulfur to Produce Sulfur Dioxide

Sulfur is burned in a deflagrating spoon in a flask, forming sulfur dioxide in the synthesis reaction.

Discussion

A flask contains water and bromphenol blue indicator. A sample of yellow powdered sulfur in a deflagrating spoon is ignited until it burns spontaneously in air with a light blue flame. The burning sulfur is then inserted into the flask. The sulfur reacts with oxygen in the flask to form sulfur dioxide gas, which then dissolves in the water, forming sulfurous acid. The solution turns to a yellow color, indicating the acid formation. As more gas dissolves in solution, the solution becomes more acidic.

S(s) + O2(g) → SO2(g) (exothermic)

SO2(g) + H2O(l) → H2SO3(aq)

Narration

Water and bromphenol blue indicator are stirred in a flask. Sulfur, an impurity of coal, is burned in a deflagrating spoon. When the spoon is inserted into the flask, sulfur dioxide is formed in the synthesis reaction. The gas dissolves, forming aqueous sulfurous acid. The formation of the acid is indicated by the color change of the solution.






Credits:
Design, Text, and Demonstration
  Tony Tautges Whitewater High School, Whitewater, WI 53190
Video and Editing
  Jerrold J. Jacobsen University of Wisconsin - Madison, Madison, WI 53706
Text
  Rachel Bain University of Wisconsin - Madison, Madison, WI 53706