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Oxidation of Ascorbic Acid

Ascorbic acid is immediately oxidized by hexacyanoferrate(III) ion.

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.7 MB, 11 seconds

File: MOVIES/TRAM12/0400110.MOV

Voiceover
A solution of potassium ferricyanide is added to water and to a 1% aqueous solution of ascorbic acid. The ascorbic acid is immediately oxidized producing a colorless solution.

Discussion
The solution of K3Fe(CN)6 is added to water as a control. This reaction demonstrates the facile oxidation of ascorbic acid, a natural antioxidant. Ascorbic acid is an example of a stable enol tautomer of a ketone.


       

Citation:  
  Martins, L. J. A.; da Costa, J. B. J. Chem. Educ. 1988, 65, pp 176-178.
Design, Text and Demonstrator:  
  Gary Trammell University of Illinois at Springfield, Springfield, IL 62794
Videographer/Editor:  
  Steve Dykema University of Illinois at Springfield, Springfield, IL 62794
Voice:  
  Margaret Biddle University of Wisconsin - Madison, Madison, WI 53706
Audio Production:  
  Greg Minix University of Wisconsin - Madison, College of Engineering, Madison, WI 53706
  Jerrold J. Jacobsen University of Wisconsin - Madison, Madison, WI 53706