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Oxidation of Glycerin with Solid Potassium Permanganate (Version 2)

Oxidation of glycerin (1,2,3-propanetriol) by potassium permanganate is demonstrated.

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2.6 MB, 36 seconds

File: MOVIES/GLYCER/GLYCER.MOV

Voiceover
A few drops of glycerin are placed into a hollow in a pile of potassium permanganate. Potassium permanganate is a strong oxidizing agent and glycerin is an easily oxidized substance. Consequently a redox type reaction is expected between these two substances. An exothermic reaction does occur with the glycerin boiling giving off smoke and eventually producing a flame that spreads around the pile of potassium permanganate. Eventually all the glycerin is consumed by the permanganate.

Discussion

14KMnO4 + 4C3H5(OH)3 --> 7K2CO3 + 7Mn2O3 + 5CO2 + 16H2O


Design:  
  John W. Moore University of Wisconsin - Madison, Madison, WI 53706
Demonstrator and Voice:  
  Kelly Houston Jetzer University of Wisconsin - Madison, Madison, WI 53706
Video:  
  Jerrold J. Jacobsen University of Wisconsin - Madison, Madison, WI 53706
Text:  
  Kelly Houston Jetzer University of Wisconsin - Madison, Madison, WI 53706
  John W. Moore University of Wisconsin - Madison, Madison, WI 53706