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Reaction of Bromine with Cyclohexane, Cyclohexene, and Benzene

Cyclohexane, cyclohexene and benzene are added to bromine. Only cyclohexene reacts with bromine under these conditions.

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1.3 MB, 20 seconds

File: MOVIES/TRAM08/0212801.MOV

Voiceover
Three test tubes contain bromine. Cyclohexane is added to the first tube, cyclohexene to the second, and benzene to the third. The red color of bromine vapor disappears from the tube containing cyclohexene. pH paper shows that hydrogen bromide is not produced in this reaction.

Discussion
This sequence demonstrates that alkanes and benzene do not react with bromine in the absence of a catalyst. Alkenes like cyclohexene undergo addition reactions with bromine to produce dibromoalkanes.


       

Design, Text and Demonstrator:  
  Gary Trammell University of Illinois at Springfield, Springfield, IL 62794
Videographer/Editor:  
  Steve Dykema University of Illinois at Springfield, Springfield, IL 62794
Voice:  
  Margaret Biddle University of Wisconsin - Madison, Madison, WI 53706
Audio Production:  
  Greg Minix University of Wisconsin - Madison, College of Engineering, Madison, WI 53706
  Jerrold J. Jacobsen University of Wisconsin - Madison, Madison, WI 53706