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Addition of Oxygen to Tetrakis(N,N-dimethylamino) Ethylene

Tetrakis(N,N-dimethylamino)ethylene is shaken with oxygen

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.8 MB, 13 seconds

File: MOVIES/TRAM06/0191606.MOV

Voiceover
A test tube of tetrakis(N,N-dimethylamino)ethylene (TMEA) is shaken with oxygen in the dark. A greenish-glow is observed.

Discussion
Tetrakis(N,N-dimethylamino)ethylene (TMEA) forms a complex with oxygen which breaks down in the presence of water or other hydroxylic solvents to produce oxidation products and an excited state of TMEA. The excited state emits light energy and returns to the ground state.


       

Citation:  
  Shakhashiri, B. Z. Chemical Demonstrations; University of Wisconsin Press: Madison, 1983; Vol. 1, pp 190-193.
Design, Text and Demonstrator:  
  Gary Trammell University of Illinois at Springfield, Springfield, IL 62794
Videographer/Editor:  
  Steve Dykema University of Illinois at Springfield, Springfield, IL 62794
Voice:  
  Margaret Biddle University of Wisconsin - Madison, Madison, WI 53706
Audio Production:  
  Greg Minix University of Wisconsin - Madison, College of Engineering, Madison, WI 53706
  Jerrold J. Jacobsen University of Wisconsin - Madison, Madison, WI 53706