JCE Software Chemistry Comes Alive!
Diels-Alder Visualization - Part 3 of 3

An animation of hybrid orbitals changing shape is presented as a simpler way to visualize the reaction.

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4 MB, 63 seconds

File: MOVIES/DIELS/DIELSC.MOV

Voiceover
It is more informative and less arbitrary to replace the three filled molecular orbitals by the six half-filled hybrid orbitals of which they are composed. Now there is no need to represent the bonds as shifting in a clockwise or counterclockwise direction.

Each hybrid merely changes its shape from pure p to sp3 and reorients slightly to overlap with a different hybrid in the new bonding pattern. Note how little real change in hybrid shape and orientation is needed in order to accomplish this three bond transformation.

Visualizing orbital interactions between molecules can explain why some chemical reactions can occur easily and others don't.


Creator:  
  Andrew Habermas University of Wisconsin - Madison, Madison, WI 53706
Executive Producers:  
  Frank Weinhold University of Wisconsin - Madison, Madison, WI 53706
  John W. Moore University of Wisconsin - Madison, Madison, WI 53706
Support:  
  National Science Foundation, Directorate for Education and Human Resource
  Institute for Chemical Education University of Wisconsin - Madison, Madison, WI 53706
  Project Seraphim University of Wisconsin - Madison, Madison, WI 53706
Writers:  
  Erica Bode Jacobsen University of Wisconsin - Madison, Madison, WI 53706
  J. Monty Wright University of Wisconsin - Madison, Madison, WI 53706
  Kelly Houston Jetzer University of Wisconsin - Madison, Madison, WI 53706
  Jerrold J. Jacobsen University of Wisconsin - Madison, Madison, WI 53706
Animation:  
  Andrew Habermas University of Wisconsin - Madison, Madison, WI 53706
  J. Monty Wright University of Wisconsin - Madison, Madison, WI 53706
  Jerrold J. Jacobsen University of Wisconsin - Madison, Madison, WI 53706
Video production, editing, and voice:  
  Jerrold J. Jacobsen University of Wisconsin - Madison, Madison, WI 53706
  Greg Minix University of Wisconsin - Madison, College of Engineering, Madison, WI 53706
  Margaret Biddle University of Wisconsin - Madison, Madison, WI 53706