Conceptual Chemistry

In a recent contribution to ChemEd X "Stoichiometry is Easy", the author states that he has "vacillated over the years between using an algorithmic method, and an inquiry-based approach to teaching stoichiometry. " I would like to suggest that there is another approach to mastering stoichiometry and that it should precede the algorithmic one: it is the conceptual approach based on a particle model to represent the species involved in chemical reactions.

Stoichiometry is Easy

This article describes a three week lesson plan for teaching stoichiometry using an algorithmic method. Two labs (one designed as a laboratory quiz) several cooperative learning exercises, student worksheets and guided instructional frameworks (forcing students to develop good habits in writing measures and doing problem solving) are included. The highlight of the lessons is the "chemistry carol" (based on Felix Mendelssohn's music for "Hark! The Herald Angels Sing") in which students recite a five-step algorithm for completing stoichiometry problems. While algorithmic processes may not always be best, I have found that there are many benefits to giving students a firm background and something to always fall back upon in one of the more challenging topics of chemistry. I believe that the good habits developed in this method of stoichiometry carry through to all the rest of their chemistry work, making it much easier to use inquiry-based methods when doing other advanced chemistry topics.

Stoichiometry Fireworks Lab Quiz

Given the amount of one reactant, students must use stoichiometry to find the ideal amount of the second reagent to use to create purple fireworks. The teacher ignites each groups' fireworks. Ideal mixture create little or no ash. Student assignment sheet with directions (and different initial amounts) plus teacher information and sample answers are included. This is an exciting and engaging activity that can be used as a stoichiometry quiz.

Time required: 

With one balance per table (two groups), the calculations should take about 10 minutes, the measures another 10 minutes. Ideally, students should be prepared to deliver their mixture to the teacher within 20 minutes. In practice, many students will take longer, particularly if the formula for potassium chlorate is not given and students are not familiar enough with ionic nomenclature.

The teacher will need about one minute per group to announce the group's mixture, ignite it, and wait for student responses. So if there are 15 groups, the teacher should allow about 15 minutes to ignite all the mixtures.

Mass of a Reaction Product

Students combine sodium carbonate and hydrochloric acid generating carbon dioxide gas which is allowed to escape. They measure the actual yield of carbon dioxide produced (missing mass), calculate the theoretical yield using stoichiometry, and then the percent yield. Students understand that 100% yield is the most appropriate answer (based on the Law of Conservation of Mass), so after considering the meaning of significant figures and the uncertainty of their measurements they are asked to decide if they did (or did not) get an answer that might indicate the validity of the Law.

Time required: 

One 50-minute period to perform the lab. One additional period to perform the calculations (optional). Often more able students will have time to begin some calculations at the end of the lab experiment.

JCE 91.10—October 2014 Issue Highlights

Communicating the Value of Chemistry The October 2014 issue of the Journal of Chemical Education is available online to subscribers [http://pubs.acs.org/toc/jceda8/91/10]. The October issue features sustainability; celebrating National Chemistry Week 2014 with articles on food and candy; increasing chemistry understanding for the nonscientist; nanochemistry; investigating materials: plastic & paper; exploring sound; research on chemical equilibrium instruction and student understanding of scale.